S a f e t y D a t a S h e e t A c c o r d i n g t o R e g u l a t i o n ( E C ) N o 1 9 0 7 / 2 0 0 6 , A n n e x I I , A m e n d e d b y C O M M I S S I O N R E G U L A T I O N ( E U ) 2 0 1 5 / 8 3 0 , A c c o r d i n g t o R E G U L A T I O N ( E C ) N o 1 2 7 2 / 2 0 0 8 White PMK920 S D S R e c o r d N u m b e r : C S S S - T C O - 0 1 0 - 1 4 2 2 6 Version 1.0 Issue date: 07-08-2024 Revision date: 07-08-2024 5 S e c t i o n 1 I d e n t i f i c a t i o n o f t h e s u b s t a n c e / m i x t u r e a n d o f t h e c o m p a n y / u n d e r t a k i n g 1 1 P r o d u c t i d e n t i f i e r : I d e n t i f i c a t i o n o n t h e l a b e l / T r a d e n a m e : A d d i t i o n a l i d e n t i f i c a t i o n : I d e n t i f i c a t i o n o f t h e p r o d u c t : I n d e x N u m b e r : R E A C H r e g i s t r a t i o n N o : 1 2 R e l e v a n t i d e n t i f i e d u s e s o f t h e s u b s t a n c e o r m i x t u r e a n d u s e s a d v i s e d a g a i n s t White PMK920 Not available See section 3 See section 3 See section 3 : 1 2 1 I d e n t i f i e d u s e s : P e n 1 2 2 U s e s a d v i s e d a g a i n s t : N o t a v a i l a b l e 1 3 D e t a i l s o f t h e s u p p l i e r o f t h e s a f e t y d a t a s h e e t : S u p p l i e r ( O n l y r e p r e s e n t a t i v e ) : S u p p l i e r ( M a n u f a c t u r e r ) : A d d r e s s : C o n t a c t p e r s o n ( E - m a i l ) : T e l e p h o n e : F a x : 1 4 E m e r g e n c y t e l e p h o n e N u m b e r - Ningbo Lofos Stationery Co., Ltd. NO.12,GANGDONGAVENUE,BEILUN, NINGBO,CHINA 20683554@qq.com +86-13567898875 - : + 8 6 - 1 3 5 6 7 8 9 8 8 7 5 O n l y a v a i l a b l e d u r i n g o f f i c e h o u r s ( 9 : 0 0 a m - 1 7 : 3 0 p m B e i j i n g T i m e Z o n e ) A v a i l a b l e o u t s i d e o f f i c e h o u r s ? S e c t i o n 2 H a z a r d s I d e n t i f i c a t i o n 2 1 C l a s s i f i c a t i o n o f t h e s u b s t a n c e o r m i x t u r e : 2 1 1 C l a s s i f i c a t i o n : T h i s p r o d u c t d o e s n o t m e e t t h e c r i t e r i a f o r c l a s s i f i c a t i o n i n a n y h a z a r d c l a s s a c c o r d i n g t o R e g u l a t i o n ( E C ) N o 1 2 7 2 / 2 0 0 8 o n c l a s s i f i c a t i o n , l a b e l l i n g a n d p a c k a g i n g o f s u b s t a n c e s a n d m i x t u r e s R E G U L A T I O N ( E C ) N o 1 2 7 2 / 2 0 0 8 H a z a r d c l a s s e s / H a z a r d c a t e g o r i e s H a z a r d c o d e s N / A N / A 2 2 L a b e l e l e m e n t s : H a z a r d P i c t o g r a m s : S i g n a l W o r d ( S ) : H a z a r d S t a t e m e n t : P r e c a u t i o n a r y s t a t e m e n t : 2 3 O t h e r h a z a r d s : N o h a z a r d p i c t o g r a m i s u s e d N o s i g n a l w o r d i s u s e d N o t a p p l i c a b l e N o t a p p l i c a b l e X Y E S N O N o t a v a i l a b l e S e c t i o n 3 C o m p o s i t i o n / i n f o r m a t i o n o n i n g r e d i e n t s S u b s t a n c e / M i x t u r e : I n g r e d i e n t ( s ) : M i x t u r e C h e m i c a l N a m e R e g i s t r a t i o n N o C A S N o E C N o C o n c e n t r a t i o n C l a s s i f i c a t i o n w a t e r N / A 7 7 3 2 - 1 8 - 5 2 3 1 - 7 9 1 - 2 4 7 % N o t c l a s s i f i e d T i t a n i u m d i o x i d e N / A 1 3 4 6 3 - 6 7 - 7 2 3 6 - 6 7 5 - 5 3 0 % N o t c l a s s i f i e d G l y c e r o l N / A 5 6 - 8 1 - 5 2 0 0 - 2 8 9 - 5 N o t c l a s s i f i e 12.99% d P r o p y l e n e G l y c o l N / A 5 7 - 5 5 - 6 2 0 0 - 3 3 8 - 0 1 0 % N o t c l a s s i f i e d I o d o p r o p y n y l b u t y l c a r b a m a t e N / A 5 5 4 0 6 - 5 3 - 6 2 5 9 - 6 2 7 - 5 H 3 0 2 ; H 3 1 7 ; H 3 1 8 ; H 3 3 1 ; H 3 7 2 ; H 4 0 0 ; H 4 1 0 0.01% ; S e c t i o n 4 F i r s t a i d m e a s u r e s 4 1 D e s c r i p t i o n o f f i r s t a i d m e a s u r e s : I n a l l c a s e s o f d o u b t , o r w h e n s y m p t o m s p e r s i s t , s e e k m e d i c a l a t t e n t i o n 4 1 1 I n c a s e o f i n h a l a t i o n : M o v e p e r s o n t o f r e s h a i r ; i f e f f e c t s o c c u r , c o n s u l t a p h y s i c i a n 4 1 2 I n c a s e o f s k i n c o n t a c t : W a s h s k i n w i t h p l e n t y o f w a t e r 4 1 3 I n c a s e o f e y e s c o n t a c t : F l u s h e y e s t h o r o u g h l y w i t h w a t e r f o r s e v e r a l m i n u t e s R e m o v e c o n t a c t l e n s e s a f t e r t h e i n i t i a l 1 - 2 m i n u t e s a n d c o n t i n u e f l u s h i n g f o r s e v e r a l a d d i t i o n a l m i n u t e s I f e f f e c t s o c c u r , c o n s u l t a p h y s i c i a n , p r e f e r a b l y a n o p h t h a l m o l o g i s t 4 1 4 I n c a s e o f i n g e s t i o n : I f s w a l l o w e d , s e e k m e d i c a l a t t e n t i o n D o n o t i n d u c e v o m i t i n g u n l e s s d i r e c t e d t o d o s o b y m e d i c a l p e r s o n n e l 4 2 M o s t i m p o r t a n t s y m p t o m s a n d e f f e c t s , b o t h a c u t e a n d d e l a y e d : T h e p r o d u c t i s n o t c l a s s i f i e d a s h a r m f u l t o h u m a n h e a l t h e f f e c t 4 3 I n d i c a t i o n o f a n y i m m e d i a t e m e d i c a l a t t e n t i o n a n d s p e c i a l t r e a t m e n t n e e d e d : S y m p t o m a t i c t r e a t m e n t S e c t i o n 5 F i r e f i g h t i n g m e a s u r e s 5 1 E x t i n g u i s h i n g m e d i a : S u i t a b l e e x t i n g u i s h i n g m e d i a : U n s u i t a b l e e x t i n g u i s h i n g m e d i a : 5 2 S p e c i a l h a z a r d s a r i s i n g f r o m t h e s u b s t a n c e o r m i x t u r e W a t e r f o g o r f i n e s p r a y D r y c h e m i c a l f i r e e x t i n g u i s h e r s C a r b o n d i o x i d e f i r e e x t i n g u i s h e r s F o a m D o n o t u s e d i r e c t w a t e r s t r e a m D u r i n g a f i r e , s m o k e m a y c o n t a i n t h e o r i g i n a l m a t e r i a l i n a d d i t i o n t o c o m b u s t i o n p r o d u c t s o f v a r y i n g c o m p o s i t i o n w h i c h m a y b e t o x i c a n d / o r 5.3 Advice for firefighters : irritating. Combustion products may include and are not limited to: Carb on monoxide. Carbon dioxide. Wear self-contained breathing apparatus for fire fighting if necessary. Section 6 Accidental release measures 6.1 Personal precautions, prot ective equipment and emergency procedures: 6.1.1 For non-emergency personnel: Keep unnecessary and unprotected personnel from entering the area Use appropriate safety equ ipment. 6.1.2 For emergency responders: Avoid skin and eye contact. Refer to section 8 of SDS for personal protection details. 6.2 Environmental Precautions: Prevent from entering into soil, ditc hes, sewers, waterways and/or groundwater. 6.3 Methods and material for Containment Absorb with liquid - binding material ( sand , diatomite , acid binders , universal and Cleaning up : binders , sawdust ). 6.4 Reference to other sections : See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. Section 7 Handling and storage 7. 1 Precautions for safe handling : 7.1.1 Protective measures: Ensure good v entilation/exhaustion at the workplace. Wash thoroughly after handling. 7.1.2 Advice on general occupational Do not eat, drink and smoke in work areas. Wash hands af ter use. Remove hygiene: contaminated clothing and protective equipment before entering eating areas. 7.2 Conditions for safe storage , including Store in cool place Containers which are opened must be carefully resealed any incompatibilities : and kept upright to prevent leakage 7.3 Specific end use (s): Not available Section 8 Exposure Controls/Personal Protection 8.1 Control parameters : 8.1.1 Occupational exposure limits: Occupational Exposure Limit Value (8-hour reference period) Occupational Exposure Limit Value (15-minute reference period Country Substance EINECS No. CAS No. ppm mg/ m3 ppm mg/ m3 Notes Finland Glyseroli 200-289-5 56-81-5 - 20 - - - Ireland Propane-1,2-diol total (vapour and particulates) particulates 200-338-0 57-55-6 150 - 470 10 - - - - - - 8.1.2 Additional exp osure limits under the Not available. conditions of use: 8.1.3 DNEL/DMEL and PNEC-Values: Not available. 8.2 Exposure controls : 8.2.1Appropriate engineering controls: Use adequate ventilation to keep airborne concentrations low. 8.2.2 Individual protection measures, such as personal protective equipment: Eye/face protection: Hand protection: Body protection: Not specified under normal conditions. Not specified under normal conditions. Not specified under normal conditions. Respiratory protection: Thermal hazards: 8.2.3 Environmental exposure controls: Not specified under normal conditions. Not specified under normal conditions. Avoid discharge into the environm ent. Dispose of rinse water in accordance with local and national reg ulations Section 9 Physical and chemical properties 9.1 Information on basic physical and chemical properties: Appearance : Colour: Odour: Odour threshold: pH: Melting point/range ( ° C): Boiling point/range ( ° C): Flash point ( ° C): Evaporation rate: Flammability limit - l ower (%): Flammability (solid, gas): Ignition temperature ( ° C): Upper/lower explosive limits: Vapour pressure (50 ° C): Vapour density : Relative Density: Bulk density (kg/m 3 ): Water solubility (g/ l): n-Octanol/Water (log Po/w): Auto-ignition temperature: Decomposition temperature: Viscosity, Explosive Oxidising dynamic (mPa.s): properties: properties: 9.2. Other information : Fat solubility ( solvent - oil to be specified ) etc: Surface tension: Dissociation constant in water( pKa): Oxidation-reduction Po tential: Liquid White Not available Not available Not available 18.17 ° C (CAS#56-81-5) 290 ° C (CAS#56-81-5) 199 ° C (CAS#56-81-5) Not available Not available Not available Not available 2.7 %-19 % (CAS#56-81-5) 0.003 mm Hg (CAS#56-81-5) Not available 1.261 g/ cm ³ (20 ° C, CAS #56-81-5) Not available 1000000 mg/L (25 ° C, CAS#56 -81-5) -1.75 (25 ° C, CAS#56-81 -5) 370 ° C (CAS#56-81-5) Not available 1412 (20 ° C, CAS#56-81-5) Not available Not available Not available Conc.:1000000 mg/L 63.4 mN/m (20 ° C, CAS# 56-81-5) Not available Not available Section 10 Stability and re activity 10.1 Reactivity: The substance is stable under normal storage and handling conditions. 10.2 Chemical stability: Stable at room temperature in closed containers under normal storage and handling conditions. 10.3 Possibility of hazardous reactions : No dangerous reactions known 10.4 Conditions to avoid : Incompatible materials 10.5 Incompatible materials : Strong oxidizing agents 10.6 Hazardous decomposition products : Carbon oxides Section 11 Toxicological info rmation 11 . 1 Information on toxicological effects : Acute toxicity : ATE mix (oral): 1250000 mg/kg ATE mix (inhalation): 15000 mg/L air ATE mix (Dermal): 550 0000 mg/kg Glycerol (CAS: 56-81-5) LD50(Oral, Rat): 18300 mg/kg bw LD50(Dermal, Rabbit): Not available LC50(Inhalation, Rat): 4655 mg-min/liter Propylene Glycol (CAS: 57-55-6) LD50(Oral, Rat): 22000 mg/kg bw LD50(Dermal, Rabbit): > 2000 mg/kg bw LC50(Inhalation, Rat): Not available Skin corrosion/Irri tation: Not classified Serious eye damage/ir ritation: Not classified Respiratory or skin sensitization: Not classified Germ cell mutagenicity: Not classified Carcinogenicity: Not classified Reproductive toxicity: Not classified STOT- single exposure: Not classified STOT-repeated exposure: Not classified Aspiration hazard: Not classified Section 12 Ecological information 12.1Toxicity: Glycerol (CAS: 56-81-5) Acute (short-term) toxicity: LC50(96h, Fish): LC50(48h, Crustacea): EC50(72h, Algae/aquatic plants): Chronic (long-term) toxi city: NOEC(Fish): NOEC(Crustacea): EC50(Algae/aquatic plants): 12.2 Persistence and degradability: 12.3 Bioaccumulative potential: 12.4 Mobility in soil: 12.5 Results of PBT and vPvB assessment: 12.6 Other adverse effects: 54000 mg/L 1955 mg/L Not available Not available Not available Not available Not available. Not available. Not available. Not available. Not available. Section 13 Disposal considerations 13.1 Waste treatment methods : The material should be disposed of by incineration in a chemical incinerator in compliance with national and regional requirements. Section 14 Transport in formation Land transport (ADR/RID) Inland waterways (ADN) Sea transport (IMDG) Air transport (ICAO/IATA) UN number Not regulated Not regulated Not regulated Not regulated UN Proper shipping name Not regulated Not regulated Not regulated Not regulated Transport hazard Class(es) Not regulated Not regulated Not regulated Not regulated Packing group Not regulated Not regulated Not regulated Not regulated Environmental hazards No No No No Special precautions for user See section 2.2 See section 2.2 See section 2.2 See section 2.2 Transport in bulk according to Annex II of Marpol and the IBC Code Not regulated Not regulated Not regulated Not regulated Section 15 Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mi xture: Relevant information regarding authorization : Not applicable. Relevant information regarding res triction: Not applicable. Other EU regulations: Employment restrictions concerning young person must be observed. For use only by technically qualified individuals. Other National regulations: Not applicable 15.2 Chemical safety assessment YES NO Section 16 Other information 16.1 Indication of changes : Version 1.0 Amended by (EU) 2015/830 16.2 Abbreviations and acronyms : ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road RID: Regulation for rail Int ernational transportation of Dangerous goods ADN: European Agreement concer ning the International Carriage of Dangerous Goods by Inland Waterways IMDG: Code international maritime dangerous goods code ICAO: International Civil Aviation Organization IATA: International Air Transport Association LC50: median lethal conc entration EC50: The effective concentration o f substance that causes 50% of the maximum response. NOEC: No Observed Effect Conce ntration DNEL : derived no - effect level PNEC: predicted no-effect concentration 16 . 3 Key literature references and sources for data ECHA Registered substances data 16.4 Training instructions : Not applicable. 16.5 Further information : This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended fo r this product. 16.6 Notice to reader : Employers should use this information only as a supplement to other information gathered by them, and should make X independent judgment of suitability of this infor mation to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Safety Data Sheet , or in combination with any other product or process, is the responsibility of the user.