SDS Report No: JCT-SDS20160422005 Date: 2016/4/22 Page 1 of 1 Add My WeChat No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 Client's Name: NINGBO TIANBO FIRST AID PRODUCT CO., LTD. Client's Address: 3 YUSHAN TOU VILLAGE, DONGQIAO TOWN, YINZHOU, NINGBO, CHINA. Product Name: BZK Job Receiving Date: 2016/4/18 Preparation Period: 2016/4/18 - 2016/4/22 Service Requested: Safety Data Sheet (SDS) Summary: As per request, the contents and formats of the SDS are prepared in accordance with US Regulations Relating to the OSHA Hazard Communication Standard 29 CFR 1910.1200. For details, please refer to the attached Safety Data Sheet (SDS). ********** Signed for and on behalf of JCT Ltd. Safety Data Sheet Page 1 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product name: BZK Product number: / 1.2 Application of the substance / the preparation End uses: / 1.3 Details of the supplier of the material safety data sheet Manufacturer/Supplier: Ningbo Tianbo First Aid Product Co.,Ltd. 3 Yushan Tou Village, Dongqiao Town, Yinzhou, Ningbo, China. Tel: +0086-574-87337575 Fax: +0086-574-87864979 E-mail: chinarbjt@vip.163.com 1.4 Emergency telephone number: Emergency Phone #: +0086-574-87337575 1.5 Reference Number: JCT-SDS20160422005 Section 2: Hazards identification 2.1 Emergency Overview OSHA Hazards Acute Tox. 4(oral) - H302; Acute Tox. 4(dermal) - H312; Skin irrt.2 - H315; Eye irrt.2 - H319; Acute Tox. 4(inhalation) - H332; Aquatic Acute 1 - H400; Target Organs No data available. 2.2 GHS Label elements, including precautionary statements Labelling Hazard pictograms Signal word Warning Safety Data Sheet Page 2 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 Hazard statements H302 H312 H315 H319 H332 H400 Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. Very toxic to aquatic life. Precautionary statement(s) P102 P233 P261 P273 P301 + P312 P304 + P340 P305+P351+P338 Keep out of reach of children. Keep container tightly closed. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Avoid release to the environment. IF SWALLOWED: Call a POISON Center or doctor/physician if you feel unwell. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 2.3 NFPA ratings (scale 0 - 4) Health hazard 2 Fire 0 Reactivity hazard 0 Special hazard 0 2.4 HMIS-ratings (scale 0 - 4) Health hazard 2 Chronic health hazard * Flammability 0 Physical hazards 0 2.5 Potential Health Effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Skin May cause skin irritation. Eyes Safety Data Sheet Page 3 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 May cause eye irritation. Ingestion May be harmful if swallowed. Section 3: Composition/information on ingredients 3.1 Substances Chemical characterization Formula: Not applicable Molecular Weight: Not applicable 3.2 Mixture Description Mixture of substances listed below with nonhazardous additions. Components Concentration(%) Classification according to GHS Aqua CAS No: 7732-18-5 EC/List No: 231-791-2 99.6 Not classified Benzalkonium chloride CAS No: 8001-54-5 EC/List No: 616-786-9 0.4 Acute Tox. 4(oral) - H302; Acute Tox. 4(dermal) - H312; Skin Corr. 1B - H314; Acute Tox. 4(inhalation) - H332; Aquatic Acute 1 - H400; Section 4: First aid measures 4.1 Description of first aid measures General advice Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice(show the label where possible). After inhalation Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. After skin contact If rash or irritation develops, discontinue use. Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Safety Data Sheet Page 4 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 After eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. After swallowing Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2 Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause drowsiness or dizziness. Symptoms/injuries after eye contact : Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. Section 5: Firefighting measures 5.1 Flammable properties Flash point(closed cup): > 93 °C (liquid) Ignition temperature: > 300 °C 5.2 Extinguishing media Suitable extinguishing agents Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media No information available. 5.3 Special hazards arising from the substance or mixture Carbon oxides. 5.4 Advice for firefighters Protective equipment Do not enter fire area without proper protective equipment, including respiratory protection. 5.5 Further information No data available. Section 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. 6.2 Environmental precautions Safety Data Sheet Page 5 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3 Methods and material for containment and cleaning up Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Dispose of contents/container to comply with applicable local, national and international regulations. Section 7: Handling and storage 7.1 Handling Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing gas, fumes, vapour or spray. Wash hands thoroughly after handling. 7.2 Storage Store in a dry, cool and well-ventilated area. Keep only in the original container in a cool, well ventilated place. Section 8: Exposure controls/personal protection Additional information about design of technical facilities: No further data; see section 7. 8.1 Control parameters Chemical Name Benzalkonium chloride CAS No: 8001-54-5 EC/List No: 616-786-9 None listed 8.2 Exposure controls Appropriate engineering controls Use with local exhaust ventilation. Ensure adequate ventilation, especially in confined areas. Personal protective equipment General protective and hygienic measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Breathing protection Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Hand protection For prolonged or repeated contact use protective gloves. Eye protection Chemical goggles or safety glasses. Safety Data Sheet Page 6 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 Skin and body protection Choose body protection according to the amount and concentration of the dangerous substance at the work place. Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water. Section 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties General Information Appearance White non woven cloth saturated with benzalkonium chloride solution. Color Colorless(liquid) Odor Slight Odor Threshold No data available pH-value 6 - 8(liquid) Melting point/freezing point 0 °C (liquid) Boiling point/boiling range 100 °C (liquid) Decomposition temperature No data available Flash point(closed cup) > 93 °C Flammability (solid, gaseous) Not applicable Ignition temperature > 300 °C Self-igniting Product is not selfigniting. Danger of explosion Product is not explosive. Explosion limits Lower Not applicable Upper Not applicable Oxidizing properties The substance does not belong to oxidizing substances. Vapour pressure No data available Density No data available Relative density/Specific gravity No data available Evaporation rate No data available Solubility in / Miscibility with Water Soluble in water(liquid) Segregation coefficient(n-octanol/water) No data available Viscosity Safety Data Sheet Page 7 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 Dynamic No data available Kinematic No data available 9.2 Other information No information available. Section 10: Stability and reactivity 10.1 Reactivity Stable under normal conditions. 10.2 Chemical stability Stable at normal temperatures and storage conditions. 10.3 Thermal decomposition No decomposition if used according to specifications. 10.4 Possibility of hazardous reactions None under normal processing. 10.5 Conditions to avoid Extremely high temperatures. 10.6 Incompatible materials Strong oxidizing agents. 10.7 Hazardous decomposition products Hydrogen chloride gas, nitrogen oxides, carbon monoxide, carbon dioxide. Section 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity LD50/LC50 values relevant for classification Chemical Name Route of exposure Type of test Species observed Dose/duration Benzalkonium chloride CAS No: 8001-54-5 EC/List No: 616-786-9 Oral Dermal LD50 LD50 Rat Rat 300 - 2000mg/kg 1420 mg/kg Primary irritant effect Skin corrosion/irritation May cause skin irritation. Serious eye damage/eye irritation Safety Data Sheet Page 8 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 May cause eye irritation. Respiratory or skin sensitization No sensitization effect. Germ cell mutagenicity No data available. Carcinogenicity Chemical Name Benzalkonium chloride CAS No: 8001-54-5 EC/List No: 616-786-9 None listed Reproductive toxicity No data available. Specific target organ toxicity - single exposure No data available. Specific target organ toxicity - repeated exposure No data available. Aspiration hazard No data available. Additional toxicological information No further relevant information available. Section 12: Ecological information 12.1 Toxicity Chemical Name Benzalkonium chloride CAS No: 8001-54-5 EC/List No: 616-786-9 LC50 - freshwater fish - 1.3 mg/l - 96 h ; 12.2 Persistence and degradability No data available. 12.3 Bioaccumulative potential Chemical Name Benzalkonium chloride CAS No: 8001-54-5 log Pow: < 3 BCF: < 100 Safety Data Sheet Page 9 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 EC/List No: 616-786-9 12.4 Mobility in soil No data available. 12.5 Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. 12.6 Other adverse effects No data available. Section 13: Disposal considerations 13.1 Waste treatment methods Recommendation - Product Follow all local, state, and federal regulations for disposal of waste chemicals. Recommendation - Uncleaned packaging Follow all local, state, and federal regulations for disposal of waste chemicals. Section 14: Transport information 14.1 UN Number DOT(US) Not restricted IMDG Not restricted IATA Not restricted 14.2 UN proper shipping name DOT(US) Not regulated IMDG Not regulated IATA Not regulated 14.3 Transport hazard class(es) DOT(US) Not regulated IMDG Not regulated IATA Not regulated 14.4 Packing group DOT(US) Not regulated IMDG Not regulated IATA Not regulated Safety Data Sheet Page 10 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 14.5 Environmental hazards DOT(US) No IMDG No IATA No 14.6 Special precautions for user No data available. Section 15: Regulatory information OSHA Hazards Acute Tox. 4(oral) - H302; Acute Tox. 4(dermal) - H312; Skin irrt.2 - H315; Eye irrt.2 - H319; Acute Tox. 4(inhalation) - H332; Aquatic Acute 1 - H400; DSL Status All components of this product are on the Canadian DSL list. SARA 302 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards May cause skin and eye irritation. Fire Hazard, Chronic Health Hazard No data available. Massachusetts Right To Know Components No data available. Pennsylvania Right To Know Components No data available. New Jersey Right To Know Components No data available. California Prop. 65 Components Safety Data Sheet Page 11 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 No data available. Section 16: Other information 16.1 Abbreviations and acronyms DOT U.S. Department of Transportation. IMDG International Maritime Code for Dangerous Goods. IMO International Maritime Organization IATA International Air Transport Association. ICAO International Civil Aviation Organization GHS Globally Harmonized System of Classification and Labelling of Chemicals. CAS Chemical Abstracts Service DNEL Derived No-Effect Level (REACH). PNEC Predicted No-Effect Concentration (REACH). LC50 Lethal concentration, 50 percent. LD50 Lethal dose, 50 percent. EC50 50% effective concentration BCF Bioconcentration factor IC50 half maximal inhibitory concentration NOEC no observed effect concentration LOEC Lowest Observed Effect Concentration IARC International Agency for Research on Cancer. STEL STEL (Short Term Exposure Limit). TWA TWA (time-weighted average). IDLH Immediately Dangerous To Life And Health ********************************************************************************************************************************************************************** The contents and format of this SDS are in accordance with 29 CFR 1910.1200(g). DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the Safety Data Sheet Page 12 of 12 29 CFR 1910.1200(OSHA) Printing Data: 2016/4/22 Revision: 2016/4/22 No.144 Huangcun Road, Dongpu Town, Tianhe District, Guangzhou, China 510665 t(86-20)22108223 f(86-20)62208986 www.gdjct.com 中国·广州·天河区东圃镇黄村路 144 号 邮编： 510665 t(86-20)22108223 f(86-20)62208986 QQ:1979344642 handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. ********************************************************************************************************************************************************************** End of Document