No. 8621.SH.1909.0024 Date: 09.11, 2019 Page: 1 / 1 T Ü V Th ü ringen CHINA Attention: please note that every statement mad e in this report is only valid for the samples tested and reported herein. This report shall not be reproduced except in full, without the written approval of the testing laboratory. Any holder of this document is advised that information contained herein ref lects the parties to a transaction from exercising all their rights and obligations under the transaction docu ments. E- mail : shanghai @ tuev - thueringen de Web https :// www tuv - thuringen com cn TUV Thuringen (Shanghai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China Test Report Applicant Address : ZHEJIANG SHULIN INFORMATION MATERIA LS CO., LTD : NO.29, SOUTH ROAD, CHANGAN TOWN, HAINING CI TY.CHINA Below information submitted by the applicant: Sample Received : 09.06, 2019 Test Period : 09.06, 2019 – 09.11, 2019 Test Requirement : Please refer to next page(s). Test Method : Please refer to next page(s). Test Result : Please refer to next page(s). Test Conclusion : Please refer to next page(s). Result Summary : Test Items 1. Material Safety Data Sheet for the submit ted samples in according to GHS Rev.3 and European Regulation No.1272/2008, No.1907/20 06 and its amendments Verdict Refer to next Jerry Zhao, Technical Director Signed for and on behalf of TUV THURINGEN SHANG HAI CO., LTD. Shanghai Name : Duo Brush Pen Inks Model : / Reference info. : / Manufacturer info. : ZSCM QUALITY DECIDES THE FUTURE Buyer info. : ZSCM QUALITY DECIDES THE FUTURE Destination : / Original : China ZHEJIANG SHULIN INFORMATION MATERIALS CO., LTD SAFETY DATA SHEET (SDS) No.29, South Road, Changan T own, Haining City.China Prepared 09.11, 2019 According to GHS Rev.3 and European Regulation No.1272/2008, No.1907/2006 and its amendments Version Ver.0 Printing Date Sep.11, 2019 Page 1 / 10 T Ü V Th ü ringen China 8621. SH .1909.0024 detail E- mail : shanghai @ tuev - thueringen de Web https :// www tuev - thueringen com TUV Thuringen (Shangh ai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China Section 1 Identification of the substance/ mixture and of the company/ undertaking 1.1 Product identifier Product form Preparation Product Name Duo Brush Pen Inks Model/Type / CAS No. Refer to section 3 Type of product Preparation Ch em i c al stru c tur e Refer to section 3 Sy n o n y m s / P r o d u c t g r o u p / 1 . 2 . 1 R e l e v a n t i d e n t i f i e d u s e s M a i n u s e c a t e g o r y i n k s f o r w a i t i n g i n s t r u m e n t s U s e o f t h e s u b s t a n c e / a r t i c l e F o r m o r e d e t a i l i n f o r m a t i o n , s e e t e c h n i c a l d a t a s h e e t 1 2 2 U s e s a d v i s e d a g a i n s t N o a d d i t i o n a l i n f o r m a t i o n a v a i l a b l e M a n u f a c t u r e r / s u p p l i e r ZHEJIANG SHULIN INFORMATION MATE RIALS CO., LTD Classification accordi ng to G l o b a l l y H a r m o n i z e d S y s t e m ( G H S ) T h e p r o d u c t i s c l a s s i f i e d a s n o h a z a r d o u s a c c o r d i n g t o t h e G l o b a l l y H a r m o n i z e d S y s t e m ( G H S ) Classification accordi ng to R e g u l a t i o n ( E C ) N o 1 2 7 2 / 2 0 0 8 ( C L P ) N o n e - a s p r o d u c t i s n o n h a z a r d o u s Classification accordi ng to ZHEJIANG SHULIN INFORMATION MATERIALS CO., LTD SAFETY DATA SHEET (SDS) No.29, South Road, Changan T own, Haining City.China Prepared 09.11, 2019 According to GHS Rev.3 and European Regulation No.1272/2008, No.1907/2006 and its amendments Version Ver.0 Printing Date Sep.11, 2019 Page 2 / 10 T Ü V Th ü ringen China 8621. SH .1909.0024 detail E- mail : shanghai @ tuev - thueringen de Web https :// www tuev - thueringen com TUV Thuringen (Shangh ai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China Hazard statements None - as product is non hazardous Precautionary statements Prevention P280 Wear protective gloves Response If medical advice is needed consult a doctor Skin contact – wash with soap and water Eye contact – rinse cautiously with water. Remove contact lenses. Ingestion – drink large amou nts of water Inhalation – supply fresh air Storage Not applicable Disposal Not applicable Additional information Not applicable 2.3 Other hazards Results of PBT and vPvT assessment PBT Not applicable vPvT Not applicable Section 3 Composition/ inform ation on ingredients No hazardous substances 3.1 Substance Not applicable 3.2 Composition Ingredient Name CAS No./RN EINECS %, by weight SC 001 Yellow 1. Glycerine 56-81-5 20.00 2. 1,2- Benzisothiazolin -3- one 2634-33-5 0.06 3. Water 7732- 18-5 75.44 4. Acid Red 87 17372-87- 1 4.50 SC 002 Yellow 1. Glycerine 56-81-5 20.00 2. 1,2- Benzisothiazolin -3- one 2634-33-5 0.06 3. Water 7732- 18-5 75.94 4. Acid Red 52 3520-42- 1 4.00 SC 003 Red ZHEJIANG SHULIN INFORMATION MATERIALS CO., LTD SAFETY DATA SHEET (SDS) No.29, South Road, Changan T own, Haining City.China Prepared 09.11, 2019 According to GHS Rev.3 and European Regulation No.1272/2008, No.1907/2006 and its amendments Version Ver.0 Printing Date Sep.11, 2019 Page 3 / 10 T Ü V Th ü ringen China 8621. SH .1909.0024 detail E- mail : shanghai @ tuev - thueringen de Web https :// www tuev - thueringen com TUV Thuringen (Shangh ai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China 1. Glycerine 56-81-5 20.00 2. 1,2- Benzisothiazolin -3- one 2634-33-5 0.06 3. Water 7732- 18-5 75.94 4. Ponceau 4R 2611-82-7 4.00 SC 004 Red 1. Glycerine 56-81-5 20.00 2. 1,2- Benzisothiazolin -3- one 2634-33-5 0.06 3. Water 7732- 18-5 75.44 4. Tartrazine 1934-21-0 4.50 SC 005 Red 1. Glycerine 56-81-5 20.00 2. 1,2- Benzisothiazolin -3- one 2634-33-5 0.06 3. Water 7732- 18-5 75.44 4. Sunset Yellow 2783-94-0 4.50 SC 006 Blue 1. Glycerine 56-81-5 20.00 2. 1,2- Benzisothiazolin -3- one 2634-33-5 0.06 3. Water 7732- 18-5 74.44 4. Brilliant Blue 3844-45-9 5.50 Section 4 First-aid measures 4.1 Description of first a id measures General advice If in doubt, get medical attention pr omptly. Show this Safety Data Sheet to the medical personnel. If inhaled No specific recommendations. If throa t irritation or coughing persists, proceed as follows. Move affected person to fresh air and keep warm a nd at rest in a position comfortable for breathing. L oosen tight clothing such as collar, tie or belt. Get medi cal attention if any discomfort continues. In case of skin contact No specific recommendati ons. Rinse with water. Get medical attention if any discomfort continues. In case of eye contact Rinse with water. Get me dical attention if any discomfort continues. If swallowing drink large amounts of water 4.2 Most important symptoms and effects, both acute and delayed No specific symptoms known. Spray/m ists may cause respiratory tract irritation. ZHEJIANG SHULIN INFORMATION MATERIALS CO., LTD SAFETY DATA SHEET (SDS) No.29, South Road, Changan T own, Haining City.China Prepared 09.11, 2019 According to GHS Rev.3 and European Regulation No.1272/2008, No.1907/2006 and its amendments Version Ver.0 Printing Date Sep.11, 2019 Page 4 / 10 T Ü V Th ü ringen China 8621. SH .1909.0024 detail E- mail : shanghai @ tuev - thueringen de Web https :// www tuev - thueringen com TUV Thuringen (Shangh ai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China 4.3 Indication of any immediate medical attention and special treatment needed Notes for the doctor: Treat symptomatically. Specific treatments: N o special treatment required. Section 5 Firefighting measures 5.1 Extinguishing media Suitable extinguishi ng media The product is not flammable. Extinguish with alcohol-re sistant foam, carbon dioxide, dry powder or water fog. Use fire- extinguishing media suitable for the surrounding f ire. Unsuitable media extinguishing Do not use water jet as an extinguisher, as this will spread the fire. 5.2 Special hazards arising from the substance or mixture Containers can burst violently or explode when heated, due to excessive pressure build-up. Hazardous decomposition products in case of fire Thermal decomposition or combustion produ cts may include the following substances: Har mful gases or vapors. 5.3 Advice for firefighters Avoid breathing fire gases or v apors. Evacuate area. Cool containers exposed to heat with water spray and remove them from the fire area if Protection during firefighting it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignite d, use water spray to disperse vapors and protect men stopping the l eak. Wear positive-pressure self-contained breathing apparat us (SCBA) and Fire Fighting Procedure appropriate protective clothing. Standard Fire fighter's clothing including helmets, protective boots and gloves will provide a basic level of protection for chemical incidents. Other information No information available Section 6 Accidental release measures 6.1 Personal precautions, protective equip ment and emergency procedures For non-emergency personnel No specific recommendations. For personal protection, see Section 8. For emergency responders No specific recommendations. For personal protection, see Section 8. 6.2 Environmental precautions Avoid discharge into drains or watercourses or onto the ground. 6.3 Methods and material for containment and cleaning up Reuse or recycle products wherever possible. Absorb spillage to prevent material damage. For containment Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillag e. Dispose of contents/container in accordan ce with national regulations. Reuse or recycle products wherever possible. Absorb spillage to For cleaning up prevent material damage. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillag e. ZHEJIANG SHULIN INFORMATION MATERIALS CO., LTD SAFETY DATA SHEET (SDS) No.29, South Road, Changan T own, Haining City.China Prepared 09.11, 2019 According to GHS Rev.3 and European Regulation No.1272/2008, No.1907/2006 and its amendments Version Ver.0 Printing Date Sep.11, 2019 Page 5 / 10 T Ü V Th ü ringen China 8621. SH .1909.0024 detail E- mail : shanghai @ tuev - thueringen de Web https :// www tuev - thueringen com TUV Thuringen (Shangh ai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China Dispose of contents/container in accorda nce with national regulations. Other information For personal protection, see Section 8. Section 7 Handling and storage 7.1 Precautions for saf e handling Read and follow manufacturer's recommendations. Wear pr otective clothing as described in Section 8 of this safety data sheet. Keep away fro m food, drink and animal feeding stuffs. Handle all packages a nd containers carefully to minimize spills. Keep container tightly sealed when not in use. Avoid the formation of mists. 7.2 Conditions for safe storage, including any incompa tibilities Technical measures and storage conditions No specific recommendations. Packaging materials Unspecified storage. Materials to avoid No specific recommendations. Further information about storage conditions No specific recommendations. 7.3 Specific end uses The identified uses for this product are detailed in Section 1.2. Section 8 Exposure controls/personal protection 8.1 Control parameters Occupational Exposure Limits No special measures required. 8.2 EXPOSURE CONTROLS Appropriate controls engineering No specific ventilation r equirements. Personal protective equipment No special measures requir ed. Eye/face protection No specific eye protection required during normal use. Large Spillages: Eyewear complying w ith an approved standard should be worn if a risk assessment indicates eye contact is possible. Skin protection No specific recommendations Body protection No specific recommendations Respiratory protection No specific recommendations Control of environmental exposure Not regarded as dangerous for t he environment. Section 9 Physical and chemical properties 9.1 Info rmation on basic physical and chemical properties Physical state ZHEJIANG SHULIN INFORMATION MATERIALS CO., LTD SAFETY DATA SHEET (SDS) No.29, South Road, Changan T own, Haining City.China Prepared 09.11, 2019 According to GHS Rev.3 and European Regulation No.1272/2008, No.1907/2006 and its amendments Version Ver.0 Printing Date Sep.11, 2019 Page 6 / 10 T Ü V Th ü ringen China 8621. SH .1909.0024 detail E- mail : shanghai @ tuev - thueringen de Web https :// www tuev - thueringen com TUV Thuringen (Shangh ai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China Appearance Liquid Color Yellow, Red, Blue Odor Odorless Odor threshold No data available pH No data available Relative evaporation rate (butylacetate=1) No data available Melting point No data available Freezing point No data available Boiling point No data available Flash point No data available Auto - ignition temperature No data available Decomposition temperature No data available Flammability (solid, gas) No data available Vapor pressure No data available Relative vapor density at 20 °C No data available Relative density No data available Density No data available Solubility No data available Log Pow No data available Viscosity, kinematic No data available Explosive properties No data available Oxidizing properties No data available Explosive limits No data available 9.2 Other information Minimum ignition energy No data available VOC content No data available Section 10 Stability and reactivity 10.1 REACTIVI TY There are no known reactivity hazard s associated with this product. 10.2 CHEMICAL STABILITY Stable at normal ambient tempe ratures and when used as recommended. Stable under the prescribed ZHEJIANG SHULIN INFORMATION MATERIALS CO., LTD SAFETY DATA SHEET (SDS) No.29, South Road, Changan T own, Haining City.China Prepared 09.11, 2019 According to GHS Rev.3 and European Regulation No.1272/2008, No.1907/2006 and its amendments Version Ver.0 Printing Date Sep.11, 2019 Page 7 / 10 T Ü V Th ü ringen China 8621. SH .1909.0024 detail E- mail : shanghai @ tuev - thueringen de Web https :// www tuev - thueringen com TUV Thuringen (Shangh ai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China storage conditions. 10.3 POSSIBILITY OF HAZAR DOUS REACTIONS No potentially hazardous reactions known. 10.4 CONDITIONS TO AVOID There are no known conditions that are likely to result in a hazardous situation. 10.5 INCOMPATIBLE MATERIALS No specific material or group of materials is likely to react with the product to produce a hazardous situation 10.6 HAZARDOUS DECOMPOSITION PRODUCTS No further relevant information available Section 11 Toxicological information 11.1 Information on toxicological effects No further relevant information available Ingestion (acute effect) Acute toxicity No further relevant information available Skin corrosion/irritation No further relevant information available Serious eye damage/eye irritation No further relevant information available Respiratory or skin sensitization No further relevant information available Germ cell mutagenicity No further relevant information available Carcinogenicity No further relevant information available Reproductive toxicity No further relevant information available Specific target organ toxicity - single exposu re No further relevant information available Specific target organ toxicity - repeated exposure No further relevant information available Aspiration hazard No further relevant information available Additional Information No further relevant information available Section 12 Ecological information 12.1 Toxicity No data available Toxicity to daphnia and ot her aquatic invertebrates No data available ZHEJIANG SHULIN INFORMATION MATERIALS CO., LTD SAFETY DATA SHEET (SDS) No.29, South Road, Changan T own, Haining City.China Prepared 09.11, 2019 According to GHS Rev.3 and European Regulation No.1272/2008, No.1907/2006 and its amendments Version Ver.0 Printing Date Sep.11, 2019 Page 8 / 10 T Ü V Th ü ringen China 8621. SH .1909.0024 detail E- mail : shanghai @ tuev - thueringen de Web https :// www tuev - thueringen com TUV Thuringen (Shangh ai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China 12.2 Persistence and degradability No further relevant information available 12.3 Bio-accumulative potential No further relevant information available 12.4 Mobility in soil No further relevant information available 12.5 Results of PBT and vPvB assessment Results of PBT assessment No further relevant information available 12.6 Other adverse effects No further relevant information available Section 13 Disposal considerations 13.1 Waste treatment methods Waste treatment methods See section 6 Waste management (disposal and evaluation) See section 6 Regulations related to waste management See section 6 Section 14 Transport information Not classified as dangerous in the meaning of transport regulations. In accordance with ADR / RID / IMDG / IATA / A DN ADR IMDG IATA AND RID 14.1 UN Number Not regulated No t regulated Not regulated Not regulated Not regulated 14.2 UN Proper shipping name Not regulated No t regulated Not regulated Not regulated Not regulated 14.3 Transport hazard class(es) Not regulated No t regulated Not regulated Not regulated Not regulated 14.4 Packing Group Not regulated No t regulated Not regulated Not regulated Not regulated 14.5 Environmental hazards No dangerous for No dangerous for No dangerous for No dangerous for No dangerous for the environment the environ ment the environment the environment the environment 14.6 Special pre cautions for user ZHEJIANG SHULIN INFORMATION MATERIALS CO., LTD SAFETY DATA SHEET (SDS) No.29, South Road, Changan T own, Haining City.China Prepared 09.11, 2019 According to GHS Rev.3 and European Regulation No.1272/2008, No.1907/2006 and its amendments Version Ver.0 Printing Date Sep.11, 2019 Page 9 / 10 T Ü V Th ü ringen China 8621. SH .1909.0024 detail E- mail : shanghai @ tuev - thueringen de Web https :// www tuev - thueringen com TUV Thuringen (Shangh ai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China Overland transport No data available Transport by sea (IMDG) No data available Air transport (IATA) No data available Inland waterway transport No data available Rail transport No data available 14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code Not dangerous according to the above s pecifications. Section 15 Regulatory information 15.1 Safety, health and environmental regulations/legislat ion specific for the substance or mixture Classification and labelling according to regulation CLP 2008 (No. 1272/2008) Classification a labelling have be en determined according to EU directive 67/548/EEC, 1999/45/EC, Regulation No.1907/2006 take into account the intended product use. 15.2 Chemical safety assessment The substance is not classified for human health hazards or for environment effects and it is not PBT or vPvB so that no exposure assessment or ri sk characterization is required. For tasks where the intervention of workers is required, the substa nce must be handled in accordance with good industrial hygiene and safety procedures. EU Regulations This safety data sheet has been prepared according to EC Regulation No. 453/2010. Th e product has been classified in accordance with EC Reg ulations, No. 1272/2008/EC, No. 1999/45/EC and No. 67/548/EEC. US Regulations TSCA Inventory Status: All of the components of this product are listed or exempt from the TSCA inventory. OSHA: None of the components in this product are considered highly hazardous by OSHA. Section 16 Other information Legislation related to safety data sheets GHS Rev.3 and European Regulation No.1272/2008, REACH Regulation No.1907/2006 Advice related to training Minimal training is recommended in order to prevent industrial risks for staff using this product and to facilitate their co mprehension and interpretation of this safety data sheet, as w ell as the label on the product. Abbreviations and acronyms ADR: European agreement concerning the internatio nal carriage of dangerous goods by road IMDG: International maritime dangerous goods code IATA: International Air Transport Association ICAO: International Civil Aviation Organisation COD: Chemical Oxygen Demand BOD5: 5-day biochemi cal oxygen demand BCF: Bioconcentration factor LD50: Lethal Dose 50 LC50: Lethal Concentration 50 ZHEJIANG SHULIN INFORMATION MATERIALS CO., LTD SAFETY DATA SHEET (SDS) No.29, South Road, Changan T own, Haining City.China Prepared 09.11, 2019 According to GHS Rev.3 and European Regulation No.1272/2008, No.1907/2006 and its amendments Version Ver.0 Printing Date Sep.11, 2019 Page 10 / 10 T Ü V Th ü ringen China 8621. SH .1909.0024 detail E- mail : shanghai @ tuev - thueringen de Web https :// www tuev - thueringen com TUV Thuringen (Shangh ai) Co. Ltd. Room C 6, Floor 16 th Jiangsu Building , No .526 Laoshan Road , Shanghai 200122, P.R. China EC50: Effective concentration 50 Log-POW: Octanol – water partition coefficient Koc: Partition coefficient of organic carbon Other information Training staff on good manufacturing practice. Manipulations are to be done only by qualified and authorized persons. Use good personal hygiene practices. SDS This information applies to the PRODUCT AS SUCH and conforming to specifications of the company. In case of formulations or mixtures, it is necessary to ascertain that a new danger will not appear. The information contained is based on our knowledge of the product, at the date of publishing and it is given quite sincerely. Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet shall only be used and reproduced for prevention and secu rity purposes. The references to leg islative, regulatory and codes of practice documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the totality of the official documents concerning the use, the possession and t he handling of the product. It is also the responsibility of the handlers of the product to pass on to any subsequent persons who will come into contact with the product. (usage, storage, cleaning of cont ainers, other processes). The totality of the information contained within this safety data sheet a nd necessary for safety at work, the protection of health and the pro tection of environment. Disclaimer The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sh eet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.